Journal articles: 'OH + fuel' – Grafiati (2024)

Abstract:

Competitive oxidation of CH₃OH to CH₂O occur via CH₃OH → CH₃O → CH₂O vs. CH₃OH → CH₂OH → CH₂O, further to COOH by the OH group via CH₂O → CHO → CO + OH → COOH vs. CH₂O + OH → CH₂OOH → CHOOH → COOH, and finally oxidation to CO₂ on Ru(0001).

Abstract:

Silicon cations and anions in a fuel-rich, premixed, methane–oxygen flame at atmospheric pressure doped with 0.01 mol% of trimethylsilane were observed by sampling the flame through a nozzle into a mass spectrometer. Twelve cations were observed which can be grouped into five series: SiOH+.nH2O (n = 0–2); SiOCH3+.nH2O (n = 0–2); Si(OH)3+.nH2O (n = 0–2); cations by nucleophilic substitution (e.g., Si(OH)(CH3)2(H2O)+); and carbonaceous aromatic cations (c-HSiCH=CH+ and c-HSiCH=CCH3+). Similarly, five anions were observed as members of two series: HxSiO3− (x = 0, 1) and HxSiO4− (x = 1–3). The chemical ionization reactions for the formation of these ions are discussed in detail, including proton transfer and also methyl cation transfer, three-body addition, nucleophilic substitution (SN2) of both the ions themselves and also their neutral silicon precursors, and H-atom abstraction reactions. The neutral silicon chemistry in the flame is dominated by SiO, but evidence was obtained from both the cation and the anion chemistry for the presence of HSiO(OH), silanoic acid; SiO(OH)2, metasilicic acid; and Si(OH)4, orthosilicic acid. The silicon ion chemistry differs markedly from the normal carbon ion chemistry that occurs naturally in the undoped methane–oxygen flame; the silicon ions show a strong tendency towards Si—O bond formation. Consideration is given to the probable structures of the various silicon cations and anions observed.

Abstract:

The paper considers science and engineering aspects of catalytically active compositions creation as regards immobilized catalysts for reforming hydrocarbon raw materials into hydrogen fuel. The authors investigate synthesis of catalytic powder mixtures and manufacturing of functional coatings by supersonic cold gas dynamic spraying. Research results in the field of creation of catalysts for steam conversion of methane to hydrogenous fuel on the metal support (Cr15Al15 tape support) are given. Composite powder mixtures (Ni–Al–Al(OH)3– Ca(OH)2–Mg(OH)2) were used as starting materials.

Abstract:

AZ31 and AZ61 magnesium alloys were discharged in 1.2mol·L-1 MgSO4 solution to investigate their performances as anode fuel material in metal-air fuel cells. The results show that aluminum in alloys takes part in the discharge process and forms the colloid of Al (OH)3. The Al (OH)3 facilitates Mg (OH)2 dropping from the surface of alloy electrode, which results in the more negative and stable discharging potential of AZ61 alloy than AZ31 alloy. The discharge efficiency of AZ31 alloy is less than AZ61 alloy because of the more server negative difference effect of AZ31 alloy.

Abstract:

The microbial fuel cell (MFC) is an innovative technology for producing electricity directly from biodegradable organic matter using bacteria. Among all the influenceable factors, anode materials play a crucial role in electricity generation. Recently, carbon nanotubes (CNTs) have exhibited promising properties as electrode material due to their unique structural, and physical and chemical properties. In this study, the impacts of CNT types in CNT-based anodes were investigated to determine their effect on both efficiency of wastewater treatment and power generation. The CNTs, namely single-walled CNT with carboxyl group (SWCNT), multi-walled CNT with carboxyl group (MWCNT-COOH) and multi-walled CNT with hydroxyl group (MWCNT-OH) were used to fabricate CNT-based anodes by a filtration method. Overall, MWCNTs provided better results than SWCNTs, especially in the presence of the -OH groups. The highest power and treatment efficiencies in MFC were achieved with an anode made of MWCNT-OH filtered on Poreflon membrane; the open circuit voltage attained was 0.75 V and the maximum power density averaged 167 mW/m2, which was 130% higher than that obtained with plain carbon cloth. In addition, MWCNT-OH is more cost-effective, further suggesting its potential to replace plain carbon cloth generally used for the MFC anode.

Abstract:

A pair of laminar, premixed, CH4–O2 flames above 2000 K at atmospheric pressure, one fuel-rich (FR) and the other fuel-lean (FL), were doped with ~10−6 mol fraction of the second-row transition metals Y, Zr, Nb, and Mo. Since these hydrocarbon flames contain natural ionization, metallic ions were produced in the flames by the chemical ionization (CI) of metallic neutral species, primarily by H3O+ and OH− as CI sources. Both positive and negative ions of the metals were observed as profiles of ion concentration versus distance along the flame axis by sampling the flames through a nozzle into a mass spectrometer. For yttrium, the observed ions include the YO+•nH2O (n = 0–3) series, and Y(OH)4−. With zirconium, they include the ZrO(OH)+•nH2O (n = 0–2) series, and ZrO(OH)3−. Those observed with niobium were the cations Nb(OH)3+ and Nb(OH)4+, and the single anion NbO2(OH)2−. For molybdenum, they include the cations MoO(OH)2+ and MoO(OH)3+, and the anions MoO3− and MoO3(OH)−. Not every ion was observed in each flame; the FL flame tended to favour the ions in higher oxidation states. Also, flame ions in higher oxidation states were emphasized for these second-row transition metals compared with their first-row counterparts. Some ions written as members of hydrate series may have structures different from those of simple hydrates; e.g., YO+•H2O = Y(OH)2+ and ZrO(OH)+•H2O = Zr(OH)3+, etc. The ion chemistry for the production of these ions by CI in flames is discussed in detail. Keywords: transition metals, ions, flame, gas phase, negative ions.

Abstract:

Addition of steam to a flame has important implications in the combustion process. The dissociation of the added steam (e.g., H2O↔H+OH, etc.) is one of the effects that contribute to the production of radical species, such as OH, H, and O, in the flame. In order to distinctly visualize two types of OH radicals produced from the fuel-air combustion reaction and that from the dissociation reaction with the added steam, we have developed a new method for planar laser-induced fluorescence spectroscopy in combination with isotope shift (herein called IS/PLIF spectroscopy). This technique has been applied to examine a methane-oxygen-nitrogen premixed flame. Two-dimensional fluorescence intensity distributions of OH radicals in the flames were monitored under three different conditions. They include without steam addition, with H2O steam addition, and with D2O steam addition. From the experimental data obtained under the three conditions, the distinction between the two types of OH radicals could be obtained. The results showed that steam addition reduced the total concentration of OH produced from the combustion and dissociation reactions and that the dissociation reaction of the added steam contributed to the production of OH. Furthermore, the results indicated that the percentage decrease in OH from fuel-air combustion reactions due to the temperature decrease effect with steam addition was almost independent of the equivalence ratio during combustion. In contrast, the percentage increase in OH produced from dissociation reaction with the steam depended on the equivalence ratio.

Abstract:

The flame emission spectrometry was applied to detect the distribution of excited radicals in two types CH4/O2 coflow jet diffusion flames (normal and inverse diffusion flames). Combining the image analysis along with the spectrometry, the chemiluminescence and structure characteristics of these diffusion flames were investigated. The results show that the inverse diffusion flame (IDF) with relatively high inlet oxygen velocity is composed of two regions: a bright base and a tower on top of the base, which is quite different from the normal diffusion flame (NDF). The flame is divided into two regions along the flame axis based on maximum OH* position (Region I: initial reaction zone; Region II: further oxidation zone). The degree of the further oxidization taking place in Region II is obvious in accordance with OH* distribution, which is the main difference in reaction zone between fuel-rich condition and fuel-lean condition for NDFs. For IDFs, the change of OH* distribution with increasing equivalence O/C ratio ([O/C]e) in Region II is not conspicuous. More OH* and CH* are generated in IDFs, due to the inner high-speed O2 flow promoting the mixing of fuel and oxygen to a certain extent.

Abstract:

ABSTRACTA 1D reactive transport model has been implemented in iCP (interface COMSOL Multiphysics and PhreeqC) to assess the corrosion of Spent Fuel (SF), considered as homogeneous UO2(am,hyd) doped with Pd. The model couples: i) generation of water radiolysis species by alpha and beta radiation considering the complete water radiolysis system with the kinetic reactions involving: H+, OH-, O2, H2O2, H2, HO2-, HO2·, O·, O-, O2-, H·, ·OH and e- ii) processes occurring in the spent fuel surface: oxidative dissolution reactions of UO2(am,hyd) and subsequent reduction of oxidized fuel, considering H2 activation by Pd, and iii) corrosion of Fe(s) in oxic and anoxic conditions. Process i) has been implemented in COMSOL and processes ii) and iii) have been implemented in PHREEQC with their kinetic constants being calibrated with different sets of experimental data published in the open literature. The model yields a UO2(am,hyd) dissolution rates similar to the values selected in safety assessments.

Abstract:

Using a spectrograph and charge-coupled device (CCD) camera, ultraviolet and visible light emission spectra were obtained from a coal-burning electric utility's cyclone furnaces operating at either fuel-rich or fuel-lean conditions. The aim of this effort is to identify light emission signals that can be related to a cyclone furnace's operating condition in order to adjust its air/fuel ratio to minimize pollutant production. Emission spectra at the burner and outlet ends of cyclone furnaces were obtained. Spectra from all cyclone burners show emission lines for the trace elements Li, Na, K, and Rb, as well as the molecular species OH and CaOH. The Ca emission line is detected at the burner end of both the fuel-rich and fuel-lean cyclone furnaces but is not detected at the outlet ends of either furnace type. Along with the disappearance of Ca is a concomitant increase in the CaOH signal at the outlet end of both types of furnaces. The OH signal strength is in general stronger when viewing at the burner end rather than the exhaust end of both the fuel-rich and fuel-lean cyclone furnaces, probably due to high, non-equilibrium amounts of OH present inside the furnace. Only one molecular species was detected that could be used as a measure of air/fuel ratio: MgOH. It was detected at the burner end of fuel-rich cyclone furnaces but not detected in fuel-lean cyclone furnaces. More direct markers of air/fuel ratio, such as CO and O2 emission, were not detected, probably due to the generally weak nature of molecular emission relative to ambient blackbody emission present in the cyclone furnaces, even at ultraviolet wavelengths.

Abstract:

The paper presents novel analytical droplet breakup criteria, on Weber number (We)-relative turbulence intensity and We-Ohnesorge (Oh) representations, based on the critical Weber number. The We-Oh analytical criterion stressed the importance of turbulence effects on We-Oh breakup criterion at high We-Oh applications. In developing the analytical models the energy criterion for a disturbed parent droplet to disintegrate and the dual-timescale for turbulent shear in droplet dispersion were considered. The present model has an advantage over to two popular droplet breakup criterion models (Pilch-Erdman and Kolev) because the present model has the ability to support a parametric investigation of droplet breakup characteristics in turbulent flow fields. The Weber-relative turbulence intensity and We-Oh analytical breakup criteria are in good agreement with published experimental data. It is envisaged that the analytical model will be incorporated into larger CFD codes for spray simulation. The continuous research in this important area will present the next generation fuel injectors for improved fuel economy of internal combustion engines, especially high-pressure direct injection engines. The model has the potential to be applied in other natural and engineering systems.

Abstract:

Steady-state performance data of DEFCs (CH₃CH₂OH and O₂) comprising the MEA containing Pt–Sn/SnO₂(33 : 7)–C anode catalyst prepared using the decal transfer method.

Abstract:

It is now known that astrocytes are not merely supporting cells but they also play an important role in neuronal funcions. Astrocytes tightly ensheat neuronal synapses and regulate the excitation of neurons by uptaking neurotransmitters; reglulate the cerebral blood flow, cerebral fluid volume and extracellular concentrations of ions. They also supply fuel in the form of lactate and provide free radical scavangers such as glutathione for active neurons. These facts indicate that impaired function of astrocytes may lead to neuronal dysfunction. After brain injury (stroke, trauma or tumors) astrocytes are swollen and release active molecules such as glutamate or free radicals resulting in neuronal dysfunction. Thus, investigation of the molecular mechanisms of astrocyte function may reveal novel targets for the development of therapeutic tools in neuronal diseases.

Abstract:

The aim of the study was to present the possibility of reducing the emission of HCl to the atmosphere and the possibility of limiting the formation of PCDD/F in the technologies of incineration of waste fuels and incineration of animal waste. Waste fuel and animal biomass were burned in a two-stage system i.e.: Io-gasification and IIo-combustion of gas products of gasification. As part of the implementation, the reduction of HCl emissions to air was investigated when Ca(OH)2 was added as an additive to the fuel from waste. Ca(OH)2 bonded HCl releasing into the gas space in the combustion process. HCl binding in the combustion chamber not only limited its emission to the atmosphere. Its elimination also limited the possibility of creating PCDD/F. In case of animal waste, HCl was captured with CaO produced from the decomposition of bone material (hydroxyapatite). The efficiency of this process was low. It was thus necessary to remove it in the built-in exhaust purification plant.

Abstract:

Improper handling of jet fuel at abandoned military bases has resulted in heavy pollution of the soil and groundwater. Experimental research of photocatalytical oxidation (PCO) of jet fuel aqueous extract and aqueous solutions of de-icing agents was undertaken. The influence of different parameters - pH, concentration of substances to be oxidised, presence of inorganic admixtures, effect of OH• radical generators - on the PCO of solutions of de-icing agents and jet fuel aqueous extract was determined. The role of OH• radicals was found to be less important in determining the PCO rate. The PCO of organic pollutants was also investigated using a catalyst immobilised onto the surface of buoyant hollow glass micro-spheres. Attached titanium dioxide (TiO2) showed lower photocatalytical activity than when suspended in slurry, although it allows waters to be treated in simple shallow ponds without intensive stirring. The biodegradability of aqueous solutions of de-icing agents and jet fuel aqueous extract increased as PCO proceeded.

Abstract:

Today there are numerous research works meant to improve nuclear fuel element performance in order to ensure reliable operation under increased burn-up conditions. In this context the pellet microstructure seems to be a very important parameter. An increase in the grain size diminishes the branching of boundaries and reduces the migration speed of gas-filled pores to the grain boundaries which are the routes of accelerated diffusion. The problem can be solved by introducing nano additives to uranium dioxide considering the influence of small addition agents upon the grain growth activation and microstructure evolution. The addition of nano particles of different powders should stimulate agglomeration process. This is one of modern tendencies in the development of new material technologies for fast reactors. In the research process the mechanical activation with simultaneous size reduction of gadolinium oxide and aluminum and gadolinium hydroxide powders (Gd2O3 №1, Gd2O3 №2, Al(OH)3 and Gd(OH)3) was done in planetary centrifugal mill "Pulverisette 5" made by Fritsch GmbH company (Germany). The technology of UO2 nuclear fuel manufacture has been developed in several variants including the agglomeration with pre-pressing or extruding, isostatic and hot pressing, rotary swaging, vibratory compacting, slip casting, etc. Today the main UO2 fuel element manufacturing technologies are cold pressing and agglomeration considering their simplicity and affordability. The conducted research permitted to ascertain some specific features of initial TiO2, Al(OH)3, Gd2O3, and Gd(OH)3 additives and determine their basic properties. The authors determined the most optimal modes of fine-grained additives production and proposed and optimal method of their introduction into UO2 mixtures. The paper also considers possible mechanisms of fine-grained additives influence on the fuel pellet production.

Abstract:

Heteropolyanion substituted layered double hydroxide were synthesized and used as catalysts for oxidative desulfurization in simulated fuel oil (dibenzothiophene (DBT) inn-octane) or diesel. The catalysts are recoverable and operate with high conversion efficiency under mild conditions of atmospheric pressure and 60 °C in a biphasic system using peroxide hydrogen as oxidant and acetonitrile as extractant. Zn9Al3(OH)24PW12O40(ZnAlPW), Zn9Al3(OH)24PMo12O40(ZnAlPMo) and Zn12Al4(OH)32SiW12O40(ZnAlSiW) were identified as effective catalysts for the oxidative removal of DBT from simulated fuel oil. The order of decreasing catalytic activity is ZnAlPMo > ZnAlPW > ZnAlSiW. The results show that the best catalysts, ZnAlPMo, attained to a DBT conversion of nearly 100%. All the catalysts can be readily recycled by filtration after use. The recoverable ZnAlPMo retains nearly the same catalytic activity as the fresh. ZnAlPMo was found to exhibit an ideal catalytic activity in oxidative desulfurization of diesel with a total sulfur removal rate of 91.8%.

Abstract:

Large eddy simulations of transcritical injection and auto-ignition of n-dodecane in a combustion chamber are performed. To this end, a diffuse-interface method is employed that solves the compressible multi-species conservation equations, and a cubic state equation together with real-fluid transport properties is employed to describe the transcritical fluid state. The reaction chemistry is represented by a finite-rate chemistry model involving a 33-species reduced mechanism for n-dodecane. Compared to commonly employed two-phase approaches, the method presented in this work does not introduce tunable parameters for spray-breakup. Large eddy simulation calculations are performed by considering the Spray A single-hole injector at non-reacting and reacting conditions at a pressure of 60 bar and temperatures between 800 and 1200 K. Quantitative comparisons with measurements for liquid and vapor penetration lengths are performed for non-reacting conditions, and sensitivity to threshold values on mixture fraction are examined. The analysis of reacting flow simulations focuses on comparisons of the instantaneous temperature and species fields for OH and CH2O at 800 and 900 K, respectively. Quantitative comparisons with measurements for ignition delay and lift-off heights as a function of ambient temperature are performed. To examine the transient ignition phase, comparisons of radially integrated OH profiles obtained from the simulations with reported measurements for OH* are performed, showing good agreement. These results show that the large eddy simulation modeling framework adequately reproduces the corresponding ignition processes, which are relevant to realistic diesel-fuel injection systems.

Abstract:

The article presents a method for determining the quality of spraying a mixture of oil and synthetic fuels obtained from the pro-cessing of polymer materials. Laboratory tests of physical parameters of such a mixture were carried out, which made it possible to determine the limit values for the volume fraction of synthetic fuels. The method of determining the suitability of this type of fuel takes into account the criterion numbers Re and Oh, which include physical parameters such as viscosity, density, and surface tension. The experimental part concerning the distribution of droplets of injected fuel and determination of Sauter Mean Diameter using laser diffrac-tion confirmed the usefulness of the developed method for the assessment of the possibility of using a mixture of petroleum-based and synthetic fuels in self-ignition engines.

Abstract:

We report a ferric-air, solid oxide battery that consists of a tubular solid oxide cell with Ca(OH)2/CaO dispersed Fe/FeOx powders integrated as the redox-active materials in the fuel chamber. The key feature here is the use of Ca(OH)2 to prevent agglomeration and coarsening of Fe/FeOx powders, and more importantly to enable in situ production of H2/H2O as the electrochemical active redox couple in the fuel electrode. The proof-of-concept solid oxide battery exhibits an energy capacity of 144 Wh kg-1-Fe at a ferric utilization of 18.8% and excellent stability in ten discharge/charge cycles with a voltage efficiency of 83% that have great potential for improvement. These results showed encouraging promise of the ferric-air, solid oxide batteries for electrical energy storage applications.

Abstract:

The recent growing attention to energy saving and environmental protection issues has brought attention to the possibility of exploiting syngas from gasification of biomass and coal for the firing of industrial plants included in the, so called, Integrated Gasification Combined Cycle power plants. In order to improve knowledge on the employ of syngas in lean premixed turbulent flames, a large scale swirl stabilized gas-turbine burner has been operated with a simplified model of H2 enriched syngas from coal gasification. The experimental campaign has been performed at atmospheric pressure, with operating conditions derived from scaling the real gas turbines. The results are reported here and consist of OH-PLIF (OH Planar Laser Induced Fluorescence) measurements, carried out at decreasing equivalence of air/fuel ratio conditions and analysed together with the mean aerodynamic characterisation of the burner flow field in isothermal conditions obtained through LDV (Laser Doppler Velocimetry) and PIV (Particle Image Velocimetry) measurements. The OH concentration distributions have been analysed statistically in order to obtain information about the location of the most reactive zones, and an algorithm has been applied to the data in order to identify the flame fronts. In addition, the flame front locations have been successively interpreted statistically to obtain information about their main features and their dependence on the air to fuel ratio behaviour.

Abstract:

The effects of orifice diameter on several aspects of diesel fuel jet flame structure were investigated in a constant-volume combustion vessel under heavy-duty direct-injection (DI) diesel engine conditions using Phillips research grade #2 diesel fuel and orifice diameters ranging from 45 μm to 180 μm. The overall flame structure was visualized with time-averaged OH chemiluminescence and soot luminosity images acquired during the quasi-steady portion of the diesel combustion event that occurs after the transient premixed burn is completed and the flame length is established. The lift-off length, defined as the farthest upstream location of high-temperature combustion, and the flame length were determined from the OH chemiluminescence images. In addition, relative changes in the amount of soot formed for various conditions were determined from the soot incandescence images. Combined with previous investigations of liquid-phase fuel penetration and spray development, the results show that air entrainment upstream of the lift-off length (relative to the amount of fuel injected) is very sensitive to orifice diameter. As orifice diameter decreases, the relative air entrainment upstream of the lift-off length increases significantly. The increased relative air entrainment results in a reduced overall average equivalence ratio in the fuel jet at the lift-off length and reduced soot luminosity downstream of the lift-off length. The reduced soot luminosity indicates that the amount of soot formed relative to the amount of fuel injected decreases with orifice diameter. The flame lengths determined from the images agree well with gas jet theory for momentum-driven nonpremixed turbulent flames.

Abstract:

This paper addresses the promoting effect of the electrooxidation of formic acid (FAO) at a nano-Pt/GC electrode in the presence of selected low molecular weight alcohols (R–OH) as blending components.

Abstract:

Spray and combustion submodels used in a Computational Fluid Dynamics (CFD) code, KIVACHEMKIN, were validated for Low Temperature Combustion (LTC) in a diesel engine by comparing measured and model predicted fuel spray penetrations, and in-cylinder distributions of OH and soot. The conditions considered were long ignition delay, early and late fuel injection cases. It was found that use of a grid independent spray model, called the GASJET model, with an improved n-heptane chemistry mechanism can well predict the heat release rate, not only of the main combustion stage, but also of the cool flame stage. Additionally, the GASJET model appropriately predicts the distributions of OH and soot in the cylinder even when the resolution of the computational mesh is decreased by half, which significantly reduces the required computational time.

Abstract:

A durable polyelectrolyte membrane with highly cross-linked aromatic packed anion-exchange sites that enable high OH⁻ ion transport, simultaneously restricting methanol cross-over for solid-state alkaline fuel cells.

Abstract:

Experiments were conducted to investigate the effect of compressibility on turbulent reacting mixing layers with moderate heat release. Side- and plan-view visualizations of the reacting mixing layers, which were formed between a high-speed high-temperature vitiated-air stream and a low-speed ambient-temperature hydrogen stream, were obtained using a combined OH/acetone planar laser-induced fluorescence imaging technique. The instantaneous images of OH provide two-dimensional maps of the regions of combustion, and similar images of acetone, which was seeded into the fuel stream, provide maps of the regions of unburned fuel. Two low-compressibility (Mc=0.32, 0.35) reacting mixing layers with differing density ratios and one high-compressibility (Mc=0.70) reacting mixing layer were studied. Higher average acetone signals were measured in the compressible mixing layer than in its low-compressibility counterpart (i.e. same density ratio), indicating a lower entrainment ratio. Additionally, the compressible mixing layer had slightly wider regions of OH and 50% higher OH signals, which was an unexpected result since lowering the entrainment ratio had the opposite effect at low compressibilities. The large-scale structural changes induced by compressibility are believed to be primarily responsible for the difference in the behaviour of the high- and low-compressibility reacting mixing layers. It is proposed that the coexistence of broad regions of OH and high acetone signals is a manifestation of a more biased distribution of mixture compositions in the compressible mixing layer. Other mechanisms through which compressibility can affect the combustion are discussed.

Abstract:

Magnesium air fuel cell (MAFC) systems are eco-friendly fuel cells that use electrolytes of saltwater and oxygen from the air to produce power. However, MAFC cells face a critical problem, which is the deposition of side products on the surface of the Mg anode plate and the cathode electrode. Therefore, this study will focus on the analysis of factor on Mg(OH)2 deposition by identifying the optimal seawater, Mg alloy, and surface roughness and additives solution. Magnesium plates AZ31 are used as the anode, and air electrode as the cathode. This study also considers physical characteristics such as SEM, EDX and corrosion test while chemical characterization by performance test with difference electrolyte, anode, and roughness. Catechol-3,5-disulfonic acid disodium salt (tiron) as anti-deposition used to reduce the deposition of Mg(OH)2 on the anode and cathode surfaces and thus improve the performance of MAFC. From the performance study, the MAFC able to produce a power density of 27.54 mW/cm2 which is high compare to the MAFC without tiron. Therefore, with the active area by 110.25 cm2, the MAFC generates 2.93 W. The deposition of Mg(OH)2 reduces the active area of magnesium oxidation, thus, reduce the electricity generation. With the knowledge of optimal seawater concentration and improvement of a single fuel cell system, this study is expecting to assist the fisheries and aquaculture sector as well as the coastal communities in terms of providing a better, safer, and cheaper alternative source of electricity.

Abstract:

Research methodology Information about Volkswagen’s human and animal testing was obtained from the secondary sources cited. Case overview/synopsis In 2014, Volkswagen (VW), BMW and Daimler funded an institute to conduct research to support their position that diesel engines are cleaner and safer than other fuel alternatives. One of the research studies conducted by the institute examined the effects of diesel fumes on humans and monkeys. Researchers put ten macaque monkeys in sealed rooms and pumped in exhaust fumes from a Volkswagen Beetle for four hours. For comparison, another group of monkeys was exposed to fumes from an older Ford pickup. The monkeys were later anesthetized and examined to see what the fumes did to their bodies. Other tests involved willing human subjects who were exposed to similar conditions. Complexity academic level This case is applicable to upper-level management or business ethics class.

Abstract:

This paper presents results from an Air Force program being conducted by researchers at Brigham Young University (BYU) Wright-Patterson Air Force Base (WPAFB), and Pratt and Whitney (P&W). This study is part of a comprehensive effort being supported by the Aero Propulsion and Power Laboratory at Wright-Patterson Air Force Base, and Pratt and Whitney in which simple and complex diffusion flames are being studied to understand better the fundamentals of gas turbine combustion near lean blowout. The program’s long-term goal is to improve the design methodology of gas turbine combustors. This paper focuses on four areas of investigation: (1) digitized images from still film photographs to document the observed flame structures as fuel equivalence ratio was varied, (2) sets of LDA data to quantify the velocity flow fields existing in the burner (3) CARS measurements of gas temperature to determine the temperature field in the combustion zone, and to evaluate the magnitude of peak temperature, and (4) two-dimensional images of OH radical concentrations using PLIF to document the instantaneous location of the flame reaction zones.

Abstract:

Various characteristics of swirling spray flames of ethanol, n-heptane, n-decane, and n-dodecane have been measured at conditions far from and close to blow-off using phase Doppler anemometry and OH* chemiluminescence, OH-planar laser-induced fluorescence, and Mie scattering at 5 kHz. The blow-off transient has also been examined. The OH* showed that the two main heat release regions lie around the spray jet at the inner recirculation zone and along the outer shear layer between the inner recirculation zone and the annular air jet. The heat release region is shortened and more attached as the flame approached blow-off. Mie images and phase Doppler anemometry data showed a wider dispersion of the ethanol spray compared to the other fuels. Similar spatial distributions of the Sauter mean diameter were observed for the four fuels for identical flow conditions, with the Sauter mean diameter value increasing with decreasing fuel volatility, but with the exception of significant presence of droplets in the nominally hollow cone for the ethanol spray. The OH-planar laser-induced fluorescence measurements showed an intermittent lift-off from the corner of the bluff body and the average lift-off height decreased with increasing air velocity, with less extinction along the inner flame branch especially for the heavier fuels. At the blow-off conditions, local extinctions appeared at both flame branches. The blow-off process followed a gradual reduction of the size of the flame, with the less volatile fuels showing a more severe flame area reduction compared to the condition far from blow-off. The average blow-off duration, [Formula: see text], calculated from the evolution of the area-integrated OH* signal, was a few tens of milliseconds and for all conditions investigated the ratio [Formula: see text] /( D/ UB) was around 11, but with large scatter. The measurements provide useful information for validation of combustion models focusing on local and global extinction.

Abstract:

Pengembangan bahan bakar nabati akan memberi berbagai manfaat bagi pembangunan nasional, antara lain pengurangan impor bahan bakar minyak dan peningkatan ketahanan energi nasional. Oleh karena itu, teknologi untuk pembuatan bahan bakar nabati pensubstitusi bahan bakar minyak, terutama bensin, merupakan kebutuhan yang mendesak. Salah satu teknologi untuk menghasilkan bahan bakar nabati pensubstitusi bensin adalah dekarboksilasi sabun hidroksi pelargonat. Magnesium hidroksi pelargonat [Mg(OH)(OOCC8H17)] dapat didekarboksilasi menghasilkan n-oktana [C8H18] dan magnesium karbonat [MgCO3] yang pada temperatur mendekati 500oC akan terurai menjadi MgO dan CO2. Penelitian ini bertujuan untuk mendapatkan pemahaman tentang dinamika dan karakter produk cair hasil reaksi dekarboksilasi sabun hidroksi pelargonat [Mg(OH)OOCC8H17] pada rentang suhu 250-350oC.The development of biofuel have a lot of advantages for national growth, such as, imports reduction of fuel and increasing national energy security and sustainability. Therefore, biofuel production technology for substitution of fuel oil especially gasoline, is very important. One of technology method to produce biogasoline is decarboxylation of pelargonic hydroxy metal soap. Magnesium hydroxy pelargonate [Mg(OH)(OOCC8H17)] can be decarboxylated to produce n-octane [C8H18] and magnesium carbonate [MgCO3] which at temperatures close to 500oC decompose into MgO and CO2. The objectives of this research is to investigate comprehensively the dynamics and character liquid products from decarboxylation of pelargonic hydroxy soap [Mg(OH)OOCC8H17] reaction at temperature range of 250-350oC.

Abstract:

This study examines the volatility distribution of organic emissions from solid fuel combustion sources from Delhi, India, and examines the chemical drivers of the OH reactivity and the secondary organic aerosol production potential.